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OpenSampling

2026 · Biomedical chromatography : BMC · paywalled

Saliva, Sweat, and Exhaled Breath as Alternative Specimens for Exercise Chemistry: Analytical Advantages, Limitations, and Comparative Progress

Pang

The finding, in our words

This narrative review finds that saliva is best suited to repeated neuroendocrine and metabolic measurements during exercise, sweat is most mature for electrolyte and sweat-rate monitoring with wearable compatibility, and exhaled breath offers access to volatile metabolism but remains instrumentally demanding. Each matrix requires matching to a defined clinical or exercise question with matrix-specific validation before translational use.

A paraphrase to the Library’s standard, never the abstract. The source is one link away and is always the authority.

Labels

  1. 2026

    This review establishes that microsampling across blood, saliva, urine and stool matrices offers validated workflows and regulatory recognition for human biomonitoring comparable to conventional methods. It finds that these decentralised approaches enhance participant acceptability and enable screening in remote or low-resource settings.

    Integrating Microsampling in Human Biomonitoring: Methodologies, Regulatory Frameworks, and Case Study InsightsRajamani & Poongavanam, Critical reviews in analytical chemistry (paywalled) · source ↗

    • wearable
    • acceptability
    • multimodal
    • sweat
    • blood
    • dbs
    • standards
    • dried
    • serology
    • colorectal
    • pediatric
    • stool
    • urine
    • validation
    • saliva
    • biomarkers
  2. 2024

    This review assesses wearable sensors for the continuous biochemical monitoring of body fluids such as sweat, saliva and interstitial fluid, confirming their potential for decentralised healthcare through pilot trials. It emphasises that successful clinical translation depends on large-scale validation and the integration of ethical and sociocultural considerations.

    Applied body-fluid analysis by wearable devicesBrasier et al., Nature (paywalled) · source ↗

    • wearable
    • multimodal
    • sweat
    • rpm
    • digital-biomarker
    • interstitial-fluid
    • validation
    • saliva
  3. 2025

    In 20 adults, CRP measured in urine and saliva strongly correlated with serum CRP (Spearman rho 0.886) and was significantly elevated in participants with systemic inflammation compared with controls, suggesting these noninvasive matrices could replace venipuncture for monitoring inflammatory status in remote or at-home settings.

    Multimodal Noninvasive Assessment of C-Reactive Protein for Systemic Inflammation in Adults: Cross-Sectional StudyShim et al., JMIR formative research · source ↗

    • venous-agreement
    • acceptability
    • multimodal
    • sweat
    • stool
    • digital-biomarker
    • urine
    • saliva
    • biomarkers
  4. 2024

    Microsampling enables less invasive, patient-centric self-collection of capillary blood for remote monitoring of metabolites and lipids, overcoming conventional venipuncture constraints. Recent device innovations address dried blood spot limitations, particularly haematocrit and volume variations, expanding decentralised applications in population health, drug discovery and multi-omics research.

    Revolutionizing Blood Collection: Innovations, Applications, and the Potential of Microsampling Technologies for Monitoring Metabolites and LipidsBossi et al., Metabolites · source ↗

    • multimodal
    • blood
    • dbs
    • metabolome
    • self-collection
    • haematocrit
    • dried
    • capillary
    • validation
    • biomarkers
    • multi-omics
  5. 2024

    The study demonstrates that frequent collection of 10 microlitres of capillary blood, combined with wearable sensor data, enables simultaneous measurement of thousands of metabolites, lipids, cytokines and proteins, revealing individualised metabolic and inflammatory responses to dietary interventions and molecular fluctuations linked to intra-day changes in heart rate, glucose, cortisol and physical activity, supporting dynamic health profiling outside the clinic.

    Multi-omics microsampling for the profiling of lifestyle-associated changes in healthShen et al., Nature biomedical engineering · source ↗

    • blood
    • capillary
    • cortisol
    • metabolome
    • biomarkers
    • wearable
    • actigraphy
    • multi-omics
    • multimodal